Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

基于F-范数的不确定性平差模型的解算方法     

鲁铁定  朱国红 《大地测量与地球动力学》2018,38(6):557-561

为提高基于F-范数的不确定性平差模型的解算效率，给出直接迭代算法进行参数估计。该算法无需SVD，解算过程简单且易于编程计算，同时给出迭代不收敛时的SVD-解方程算法。二元线性拟合及沉降观测AR模型的算例结果表明，这2种算法正确可行，与SVD-迭代算法具有等价性。当迭代收敛时，宜使用直接迭代算法，收敛速度更快，解算效率更高；当迭代不收敛时，可釆用SVD-解方程算法。  相似文献   

黄河流域气候与农业种植面积变化对径流的影响     

李华贞  张强  顾西辉  史培军 《湖泊科学》2018,30(4):1138-1151

根据黄河流域1960—2005年5个水文站逐日流量、77个气象站1959—2013年逐日降水数据,结合流域内主要农作物种植面积及大型水库资料,全面探讨气候与农业面积变化及人类活动对黄河流域径流变化的影响.研究表明:黄河流域所有流量分位数总体呈下降趋势,并于1980s中后期到1990s中期发生突变.降水变化是黄河流域径流变化的主要影响因素.在考虑不同流量分位数情况下,农作物种植面积变化对不同分位数径流变化的影响也有差异性.花园口站农作物种植面积变化对径流量量级和可变性均有显著影响;其余4站各项气候变化与农作物种植指标参数较大,虽均未达到10%的显著性水平,但仍会对径流的量级变化产生影响.对唐乃亥站,农作物耕作面积的下降减少了灌溉用水,在0.5流量分位数时有高达60%增加径流量的间接作用.对于头道拐站,农作物耕作面积的增加使得流域总蒸发量增加,灌溉用水增加,在0.3流量分位数时有高达40%减少径流量的间接作用.该研究为气候变化与人类活动影响下黄河流域水资源优化配置提供重要理论依据.  相似文献   

呼和浩特市生境质量对城市用地扩展的时空响应          下载免费PDF全文

冯琰玮  甄江红  马晨阳 《干旱区地理》2020,43(4):1014-1022

以呼和浩特市为研究区,采用梯度分析法,结合InVEST模型,在评价研究区近27 a城市用地扩展及生境质量演变的基础上,运用双变量空间自相关剖析生境质量对城市用地扩展的时空响应。结果表明：（1） 研究时段内,城市扩展表现为核心区的低密度扩张及外围区的多点扩散,紧凑度不断下降,城市结构不稳定,扩展模式不尽合理。（2） 生境平均值从0.49下降到0.44,质量等级跌至较差水平。低等级生境主要呈圈层向南部、东南部扩散,与建设用地扩展方向基本一致。（3） 建设用地扩展强度与生境质量变化空间分布呈负相关关系,核心外围区的建设用地扩展始终为变化最强烈的地带,生境质量退化也最为剧烈。（4） 斑块密度不断上升,特别是建设用地斑块的增加使得城市景观格局愈发破碎。  相似文献   

基于 SRP 概念模型的祁连山地区生态脆弱性评价   总被引：1，自引：0，他引：1       下载免费PDF全文

刘佳茹  赵军  沈思民  赵彦军 《干旱区地理》2020,43(6):1573-1582

基于生态敏感性-生态恢复力-生态压力度（SRP）概念模型，从地形、气候、植被和社会经济 因子选取 8 个评价指标，利用遥感和 GIS 技术，采用主成分分析方法求取权重，对祁连山地区启动 水源涵养区生态环境保护和综合治理规划研究前后近 10 a 的生态脆弱性程度进行系统、定量地评 估，旨在揭示生态脆弱性的分布特征、时空演变及动因，为区域生态保护、资源利用和可持续发展 提供参考。结果表明：（1）从研究区生态脆弱性分布来看，祁连山地区主要以轻度和重度脆弱为 主，脆弱性程度从西北向东南地区逐渐减弱，西北地区植被覆盖度小，海拔高，生态环境较为恶劣 是导致脆弱性程度较高的原因；（2）祁连山地区 3 期生态脆弱程度呈逐渐下降趋势，综合指数分别 为 3.307、3.118 和 3.103；2005 年 生 态 脆 弱 性 较 高 ，极 度 脆 弱 面 积 为 28 610 km²，2010 年 下 降 为 11 723 km²，2015 年降低为 6 174 km²，极度脆弱面积逐渐减少；（3）从祁连山地区生态脆弱性演变动 因来看，8 个指标对生态脆弱性影响均较为显著，但在不同的时间影响程度各不相同，2005—2015 年 3 期数据中对生态脆弱性影响最大的均为植被指数，降水次之，地形因子影响最小。总体来看， 近年来祁连山地区生态脆弱性程度有所降低，但仍然需要加强保护力度，促进生态环境可持续 发展。  相似文献   

科尔沁湿草甸参考作物蒸散发模拟分析     

李霞  刘廷玺  段利民  王冠丽  童新  周亚军  杨晓君 《中国沙漠》2020,40(2):134-143

为探明气候变化下干旱半干旱地区湿草甸参考作物蒸散发(ET₀)影响因子,使用FAO 56 P-M模型对科尔沁湿草甸ET₀进行模拟,利用涡度相关系统对模型的适用性进行评价,并通过通径分析及指标敏感性分析对ET₀的影响因子进行辨识。结果表明:(1)小时尺度模拟精度最高,日尺度次之,月尺度较差,小时尺度上晴、阴、雨3种天气条件下模拟效果不同,晴天最优,阴雨天较差。(2)ET₀年内变化呈单峰曲线状,生长季明显高于非生长季,集中在3—10月,占全年89.79%。生长季典型晴天ET₀逐小时分布特征遵循倒“U”单峰型变化规律。(3)通径分析结果显示,对ET₀的通径系数以及对回归方程估测可靠程度E的总贡献均表现为VPD(饱和水汽压差) > T_min(最低气温) > R_n(冠层表面净辐射)>u₂(2 m高度风速),即VPD为影响ET₀最重要的因子;指标敏感性分析中,在去除VPD后引起的E变化最大,说明ET₀对VPD的变化最为敏感,其次为u₂、T_min和R_n。  相似文献   

基于住房需求意愿的广州市中产阶层住房区位选择     

边艳  周春山  胡锦灿 《热带地理》2020,40(5):832-842

以2014年广州市中产阶层聚居区24个街道、50个社区进行的问卷调查和深度访谈资料为数据源，从住房需求意愿与区位选择方面分析了广州中产阶层住房选择，并运用多元Logistic回归分析法对其影响因素进行研究。研究发现：1）广州市中产阶层住房区位选择表现出明显的“向中心城区”性；2）现居住现状（人均住房面积、现小区区位、现小区建成年代、现居住时间）、家庭生命周期（年龄、家庭规模、子女数量）和经济水平（家庭年总收入、个人年总收入、私家车拥有量）等因素对中产阶层住房需求意愿具有显著影响；3）家庭生命周期（年龄、家庭规模）、个体因素（教育程度、户籍地）等要素对中产阶层住房区位选择具有显著影响。4）制度因素、区位因素和个体因素共同影响着广州市中产阶层住房区位选择。  相似文献   

“一带一路”背景下的中国与巴基斯坦的贸易关系演进及其影响因素     

宋周莺  祝巧玲 《地理科学进展》2020,39(11):1785-1797

中巴经济走廊是“一带一路”6大经济走廊之一,而贸易畅通是“一带一路”建设的核心环节。研究中巴贸易关系演变及其影响因素、分析其贸易潜力,对推进“一带一路”建设具有重要的示范作用。论文从中巴贸易发展态势、商品结构、空间格局等方面揭示中巴贸易关系,运用随机前沿引力模型分析中巴贸易关系的主要影响因素、并探析其发展潜力,以期为推进中巴经济走廊建设提供科学支撑。研究发现：① 中巴贸易发展迅速,中对巴贸易顺差持续扩大;中国主要出口机械及电气设备等资本密集型产品,主要进口纺织原料及纺织制品等初级产品和劳动密集型产品。② 中国各省份与巴基斯坦的贸易合作存在明显的空间差异,东部沿海省份与巴贸易联系较紧密,西部各省份除新疆外与巴基斯坦贸易额均较小。③ 中国多数省份对巴贸易商品结构发生显著变动,其中,新疆、山东等进出口商品结构多元的省份的变动相对较小。④ 中国各省份的经济发展水平和市场规模对中巴贸易拉动较强;海运距离对中巴贸易规模有显著的负向影响;领土接壤为中巴组织边境贸易提供了良好条件;铁路和水运口岸的建设对中巴贸易具有积极影响。⑤ 中国各省份与巴基斯坦均有较大贸易潜力,内蒙古、云南、广西、陕西等省份的合作潜力更明显。  相似文献   

Analysis of city centrality based on entropy weight TOPSIS and population mobility:A case study of cities in the Yangtze River Economic Belt     

罗静  陈四云  孙璇  朱媛媛  曾菊新  陈广平 《地理学报(英文版)》2020,30(4):515-534

Based on statistical data and population flow data for 2016,and using entropy weight TOPSIS and the obstacle degree model,the centrality of cities in the Yangtze River Economic Belt(YREB)together with the factors influencing centrality were measured.In addition,data for the population flow were used to analyze the relationships between cities and to verify centrality.The results showed that:(1)The pattern of centrality conforms closely to the pole-axis theory and the central geography theory.Two axes,corresponding to the Yangtze River and the Shanghai-Kunming railway line,interconnect cities of different classes.On the whole,the downstream cities have higher centrality,well-defined gradients and better development of city infrastructure compared with cities in the middle and upper reaches.(2)The economic scale and size of the population play a fundamental role in the centrality of cities,and other factors reflect differences due to different city classes.For most of the coastal cities or the capital cities in the central and western regions,factors that require long-term development such as industrial facilities,consumption,research and education provide the main competitive advantages.For cities that are lagging behind in development,transportation facilities,construction of infrastructure and fixed asset investment have become the main methods to achieve development and enhance competitiveness.(3)The mobility of city populations has a significant correlation with the centrality score,the correlation coefficients for the relationships between population mobility and centrality are all greater than 0.86(P<0.01).The population flow is mainly between high-class cities,or high-class and low-class cities,reflecting the high centrality and huge radiating effects of high-class cities.Furthermore,the cities in the YREB are closely linked to Guangdong and Beijing,reflecting the dominant economic status of Guangdong with its geographical proximity to the YREB and Beijing's enormous influence as the national political and cultural center,respectively.  相似文献   

Post-earthquake economic resilience and recovery efficiency in the border areas of the Tibetan Plateau: A case study of areas affected by the Wenchuan Ms 8.0 Earthquake in Sichuan,China in 2008     

Zhou  Kan  Liu  Baoyin  Fan  Jie 《地理学报(英文版)》2020,30(8):1363-1381

Journal of Geographical Sciences - The border areas of the Tibetan Plateau and the neighboring mountainous areas have a high incidence of earthquakes with a magnitude greater than Ms 5.0, as well...  相似文献